Hey buddy. I'm assuming you have no lightning detection rig.
Ideally you need a tripod or base of somesort (to steady the camera).
Set the camera to timer (so you don't jog it when pressing shoot)
Set to manual focus (focus towards a far away object using your live view - or in cam if you can).
So basically what you want to do (ideally) is keep the shutter open for as long as possible. In both day and night instances. More chance of catching a strike.
During the day it means -
ISO 100 (or less),
Very small aparture (F16 or more - although if you go too high you'll get defraction softness).
At those settings in current light - approx. 1/60 second should give a balanced exposure.
Now you'll want to just keep shooting away (or set the camera to auto shoot for a given time - say 1 shot per 2-3 seconds, whatver works).
Without a lightning detector you won't know when lightening will strike so you'll have to be lucky.
During the night - much easier.
Keep settings as i said...ISO 100, F16, Timer (or remote), Manual focus.
You want a shutter speed of around 6-8 seconds. Thats much more time to get a strike.
Its best to use a remote in both instances as you won't touch the camera and risk a jog.
OH AND REMOVE ALL METAL OBJECTS FROM YOUR PERSON. ALSO WATCH OUT USING A TRIPOD.
IF YOU CAN, USE AN IN CAR CLAMP OR A JOBI GORILLA POD CLAMPED TO YOUR CAR WINDOW.
SORRY...CAN'T STRESS THIS ENOUGH - TRIPODS ATTRACT ELECTRICITY!